Chandra, Amreesh and Singh, D. P. and Singh, P. K. and Khare, Neeraj and Chandra, S. (2006) Ionic noise measurement in polymer electrolytes. Ionics , 12. pp. 349-352. ISSN 0947-7047

[img] PDF - Published Version
Restricted to Registered users only

Download (124Kb) | Request a copy

Abstract

Electrical noise associated with ion transport (termed as "ionic noise") has been measured at different temperatures, using a lock-in amplifier and dynamic signal analyzer for a polymer electrolyte PEO:NH4I and its US dispersed composite. The ionic noise suddenly increases as the polymer passes through its phase transition at T-g and T-m. The T-g-peak in the noise measurement appears more clearly than what it does in DTA/DSC or conductivity measurements. Therefore, we suggest the noise technique as a good probe for studying phase transitions in ion conducting solid electrolytes. Further, the present noise measurements also confirm the known results of DTA/DSC studies that both T-g and T-m of polymer electrolytes shift on the formation of composites.

Item Type: Article
Additional Information: Copyright for this article belongs to M/s Springer Verlag.
Subjects: Electrochemistry
Physical Chemistry/Chemical Physics
Physics
Divisions: UNSPECIFIED
Depositing User: Users 27 not found.
Date Deposited: 11 May 2018 05:10
Last Modified: 11 May 2018 05:10
URI: http://npl.csircentral.net/id/eprint/2495

Actions (login required)

View Item View Item