Patel, Ch. Ravi Prakash and Tripathi, Prashant and Singh, Sweta and Singh, Avanish Pratap and Dhawan, S. K. and Kotnala, R. K. and Gupta, Bipin Kumar and Srivastava, O. N. (2016) New emerging radially aligned carbon nano tubes comprised carbon hollow cylinder as an excellent absorber for electromagnetic environmental pollution. Journal of Materials Chemistry C, 4 (23). 5483-5490 . ISSN 2050-7526

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Abstract

Herein, we demonstrated the synthesis of a hollow cylinder with a new architecture of up to several centimeters in diameter and several centimeters long and having similar to 100 mm wall thickness. The hollow carbon cylinder was formed by radially aligned CNTs. These CNTs were grown on ferrocene derived Fe nanoparticles deposited throughout the inner wall of the quartz growth tube. This new ingenious carbon architecture was grown by a customized spray pyrolysis method. Furthermore, we also synthesized such carbon hollow cylinders using different precursor concentrations (ferrocene: benzene), different phases and microstructures to evaluate their EMI shielding effectiveness. The structural and microstructural characterizations of these hollow carbon cylinders comprising radially aligned CNTs were examined through various techniques, including XRD, Raman, FTIR, XPS, SEM, TEM, and HRTEM spectroscopy. Furthermore, the magnetic measurements (M-H) were performed for such structures to probe the magnetic properties of these carbon hollow cylinders for different concentrations. Furthermore, the EMI shielding through different concentrations of Fe bearing CNTs were explored in detail for tailoring the desired shielding effectiveness value for possible potential applications. Hence, our synthesis method provides a unique architecture for promising next generation building blocks in the form of carbon hollow cylinders made up of radially aligned CNTs over the conventional randomly oriented CNTs. This could be directly used to make it as a co-axial cover for electrical cables to protect them from EMI pollutants.

Item Type: Article
Additional Information: Copyright for this article belongs to M/s Royal Society of Chemistry.
Subjects: Materials Science
Applied Physics/Condensed Matter
Divisions: UNSPECIFIED
Depositing User: Dr. Rajpal Walke
Date Deposited: 07 Mar 2018 06:53
Last Modified: 07 Mar 2018 06:53
URI: http://npl.csircentral.net/id/eprint/2301

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