Jeyakumar, R. and Gu, Z. and Sivoththaman, S. and Nathan, A. (2012) Synthesis and characterization of low-k films for large area imaging applications. Microelectronic Engineering, 99. 58-61. ISSN 0167-9317

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Abstract

An organic liquid polymer based on methyltriethoxysilane has been synthesized. The material;when spin-coated onto wafers and thermally treated;lead to dielectric films of low permittivity;which can be used in hydrogenated amorphous silicon (a-Si:H) thin film transistor (TFT) based large area imaging arrays as an inter-level dielectric between the TFT and pixel levels. Fourier Transform Infrared Spectroscopy (FTIR) shows prominent peaks of Si-CH3 stretch and Si-O stretch modes. The dielectric constant (k) of the film was found to decrease with increasing curing temperature (T-cure). However;k values were < 3 for T-cure < 260 degrees C;which is the upper limit for our a-Si:H process. Thermogravimetric analysis showed that major weight loss takes place for up to 200 degrees C;and the film stabilizes thereafter. The stress in the films was found to be compressive;and increased from 50 to 220 MPa when T-cure was increased from 250 to 450 degrees C. The low stress for low T-cure is a desirable property for film integration.

Item Type: Article
Additional Information: copyright for this article belongs to M/s Elsevier
Subjects: Engineering > Electronics and Electrical Engineering
Applied Physics/Condensed Matter
Nanoscience/ Nanotechnology
Optics
Divisions: UNSPECIFIED
Depositing User: Users 27 not found.
Date Deposited: 19 Aug 2026 10:55
Last Modified: 19 Aug 2026 10:55
URI: https://npl.csircentral.net/id/eprint/3384

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