Kumar, Gagan and Sharma, Sucheta and Kotnala, R. K. and Shah, Jyoti and Shirsath, Sagar E. and Batoo, Khalid M. and Singh, M. (2013) Electric, dielectric and ac electrical conductivity study of nanocrystalline cobalt substituted Mg-Mn ferrites synthesized via solution combustion technique. Journal of Molecular Structure, 1051. 336-344. ISSN 0022-2860

PDF - Published Version Restricted to Registered users only Download (1601Kb) | Request a copy

Abstract

Nanosized cobalt substituted Mg-Mn ferrites with a chemical composition Mg0.9Mn0.1CoxFe2-xO4 (x = 0.0, 0.1, 0.2 and 0.3) were synthesized for the first time by solution combustion technique. X-ray diffraction (XRD) technique was used to confirm the phase formation and it revealed the formation of single phase cubic spinel structure. The surface morphology of samples was studied by using scanning electron microscopy (SEM). The dc resistivity of nanoferrites was studied as a function of temperature which indicates the semiconducting nature of nanoferrites. The dielectric properties such as dielectric constant and dielectric loss have been investigated as a function of frequency and temperature. The dielectric constant and dielectric loss were found to increase with an increase in temperature whereas with an increase in frequency both are observed to decrease. AC electrical conductivity was found to increase with an increase with frequency and temperature. Impedance spectroscopy technique was used to study the effect of grain and grain boundary on the electrical properties of the prepared samples. A very low value of dielectric loss even at high frequencies and high value of dc resistivity (10(8) Omega cm) are the cardinal achievements of the present work which make these nanoferrites suitable for microwave applications.

Item Type:	Article
Additional Information:	copyright for this article belongs to M/s Elsevier
Subjects:	Chemistry > Physical Chemistry
Divisions:	UNSPECIFIED
Depositing User:	Users 27 not found.
Date Deposited:	19 Aug 2026 10:12
Last Modified:	19 Aug 2026 10:12
URI:	https://npl.csircentral.net/id/eprint/3259

Actions (login required)

View Item