Dalai, M. K. and Kundu, R. and Pal, P. and Bhanja, M. and Sekhar, B. R. and Martin, C. (2011) XPS study of Pr1−xCaxMnO3 (x = 0.2, 0.33, 0.4 and 0.84). Journal of Alloys and Compounds, 509 (29). pp. 7674-7676. ISSN 0925-8388
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Official URL: http://dx.doi.org/10.1016/j.jallcom.2011.05.003
Abstract
We have studied the Mn 2p, Ca 2p, and Pr 4d core levels of Pr1–xCaxMnO3 (x = 0.2, 0.33, 0.4 and 0.84) as a function of x using X-ray photoelectron spectroscopy both at room temperature as well as 77 K. Suppression of chemical potential shifts have been observed at 77 K compared to that of room temperature spectra. We have discussed this result by considering the concept of phase separation.
Item Type: | Article |
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Additional Information: | Copyright for this article belongs to M/s Elsevier B.V. |
Uncontrolled Keywords: | Colossal magnetoresistance; Photoelectron spectroscopy; Chemical shift; Phase separation |
Subjects: | Chemistry Materials Science > Materials Science Metallurgy & Metallurgical Engineering |
Divisions: | UNSPECIFIED |
Depositing User: | Mr. Abhishek Yadav |
Date Deposited: | 27 Sep 2012 12:11 |
Last Modified: | 27 Sep 2012 12:11 |
URI: | http://npl.csircentral.net/id/eprint/609 |
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