Vijayan, N. and Rani, N. and Madhurambal, G. and Bhagavannarayana, G. and Rathi, B. and Philip, R. and Safakath, K. and Mojumdar, S. C. (2013) Synthesis, growth, and characterization of iminodiacetic acid monohydrochloride. Journal of Thermal Analysis and Calorimetry, 112. pp. 1113-1119. ISSN 1388-6150

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Abstract

The title compound of iminodiacetic acid hydrochloride (IDAAMHCL) has been successfully synthesized by adopting conventional chemical reaction and the single crystals have been grown by solvent evaporation method at room temperature and studied its various properties and reported for the first time. The lattice dimension and the crystal structure were identified from the powder X-ray diffraction analysis. The crystalline perfection assessed by high resolution X-ray diffraction technique shows that the specimen is free from structural grain boundaries. The presence of functional groups and the protons in IDAAMHCl was confirmed by Fourier transform infra-red and NMR (H-1 and C-13) spectroscopic techniques. The presence of carbon, hydrogen, and nitrogen was confirmed by elemental analysis. The optical behavior of IDAAMHCl was assessed by UV-visible spectroscopy and it is found that there is no absorption in the entire visible region of the spectrum. The Z scan measurements at 532 nm with 5 ns laser pulses show that IDAAMHCL is a very good candidate for optical limiting applications.

Item Type:	Article
Additional Information:	Copyright for this article belongs to M/s Springer Verlag.
Subjects:	Chemistry > Analytical Chemistry Applied Physics/Condensed Matter Thermodynamics
Divisions:	UNSPECIFIED
Depositing User:	Users 27 not found.
Date Deposited:	03 Jun 2020 10:32
Last Modified:	03 Jun 2020 10:32
URI:	http://npl.csircentral.net/id/eprint/3007

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