Chavan, Pradeep and Naik, L. R. and Belavi, P. B. and Chavan, G. N. and Kotnala, R. K. (2017) Synthesis of Bi3+ substituted Ni-Cu ferrites and study of structural, electrical and magnetic properties. Journal of Alloys and Compounds, 694. pp. 607-612. ISSN 0925-8388

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Bi3+ substituted Ni-Cu ferrites with the particles size 0.28 mu m-0.53 mu m were prepared by solid state reaction method. X-ray diffraction analysis confirmed the single phase cubic spinel structure with the space group of Fd(3m)-O-7(h). IR absorption bands assigned at 580 cm(-1) and 403 cm(-1) corresponds to the stretching of vibrations of tetrahedral and octahedral complexes of the ferrites. The average grain sizes of the ferrites were estimated by SEM micrographs at around 1.04 mu m which was found to be increased with Bi content. The decrease of DC resistivity as a function of temperature shows the semiconducting nature of ferrites and is attributed to the increase in thermally activated drift mobility of charge carriers. The dielectric constant decreases with increase in the frequency of all samples shows dispersion behavior. Hysteresis loop of the ferrites at room temperature were studied for the determination of saturation magnetization and magnetic moment. The maximum saturation magnetization obtained is about 41.27emu/gm for Ni0.5Cu0.5Fe2O4 ferrite.

Item Type: Article
Additional Information: Copyright for this article belongs to M/S Elsevier.
Subjects: Chemistry > Physical Chemistry
Materials Science
Metallurgy & Metallurgical Engineering
Depositing User: Users 27 not found.
Date Deposited: 08 May 2019 08:20
Last Modified: 08 May 2019 08:20

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