Tang, Qun and Li, Peng-Fei and Zou, Zhi-Ming and Liu, Zheng and Liu, Shu-Xia (2017) A novel cryogenic magnetic refrigerant metal-organic framework based on 1D gadolinium(III) chain. Journal of Solid State Chemistry, 246. pp. 329-333. ISSN 0022-4596

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A metal-organic framework (MOF) based on gadolinium ion (Gd3+) and tricarboxylate ligand, [Gd(BTPCA) (H2O).2DMF.3H(2)O (Gd-BTPCA) (H(3)BTPCA =1,1',1'-(benzene-1,3,5-triyl)tripiperidine-4-carboxylic acid; DMF=dimethylformamide), was synthesized and structurally characterized. The adjacent Gd3+ ions are intraconnected by the carboxylate groups of the BTPCA(3-) ligands to form a 1D Gd3+ ion chain. The 1D Gd3+ ion chains are interconnected by the BTPCA3-ligands, giving rise to a 3D framework with 1D open channel. The magnetic studies indicate that Gd-BTPCA exhibits weak ferromagnetic interactions, and acts as a cryogenic magnetic refrigerant having the magnetic entropy change (-Delta S-m) of 20.40 J kg(-1) K-1 for Delta H =7 T at 3 K.

Item Type: Article
Additional Information: Copyright for this article belongs to M/s Elsevier.
Subjects: Chemistry > Inorganic Chemistry
Chemistry > Physical Chemistry
Depositing User: Users 27 not found.
Date Deposited: 14 Aug 2018 11:54
Last Modified: 14 Aug 2018 11:54
URI: http://npl.csircentral.net/id/eprint/2609

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