Srivastava, Rajesh Kr. and Xingjue, Wang and Kumar, Vinod and Srivastava, Anchal and Singh, Vidya Nand (2014) Synthesis of benzimidazole-grafted graphene oxide/multi-walled carbon nanotubes composite for supercapacitance application. Journal of Alloys and Compounds, 612. 343-348 . ISSN 0925-8388

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Abstract

We are reporting the fabrication, characterizations and supercapacitance performance of benzimidazole-grafted graphene oxide/multi-walled carbon nanotubes (BI-GO/MWCNTs) composite. The synthesis of BI-GO materials involves cyclization reaction of carboxylic groups on GO among the hydroxyl and amino groups on o-phenylenediamine. The BI-GO/MWCNTs composite has been fabricated via in situ reduction of BI-GO using hydrazine in presence of MWCNTs. Scanning electron microscopy (SEM), Transmission electron microscopy (TEM), Raman spectroscopy, X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR) have been used to characterize its surface and elemental composition. The uniform dispersion of MWCNTs with BI-GO helps to improve the charge transfer reaction during electrochemical process. The specific capacitance of BI-GO/MWCNTs composite is 275 and 460 F/g at 200 and 5 mV/s scan rate in 1 mol/L aqueous solution of H2SO4. This BI-GO/MWCNTs composite has shown 224 F/g capacitance after 1300 cycles at 200 mV/s scan rate, which represents its good electrochemical stability.

Item Type: Article
Additional Information: Copyright for this article belongs to M/S Elsevier.
Uncontrolled Keywords: Graphene Carbon nanotubes Supercapacitor
Subjects: Materials Science
Metallurgy & Metallurgical Engineering
Divisions: UNSPECIFIED
Depositing User: Dr. Rajpal Walke
Date Deposited: 23 Nov 2015 09:49
Last Modified: 23 Nov 2015 09:49
URI: http://npl.csircentral.net/id/eprint/1591

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