Pandey, Sugandha Dogra and Samanta, K. and Singh, Jasveer and Sharma, Nita Dilawar and Bandyopadhyay, A. K.
(2014)
Raman scattering of rare earth sesquioxide Ho2O3: A pressure and temperature dependent study.
Journal of Applied Physics, 116 (13).
ISSN 0021-8979
Abstract
Pressure and temperature dependent Raman scattering studies on Ho2O3 have been carried out to investigate the structural transition and the anharmonic behavior of the phonons. Ho2O3 undergoes a transition from cubic to monoclinic phase above 15.5 GPa, which is partially reversible on decompression. The anharmonic behavior of the phonon modes of Ho2O3 from 80K to 440K has been investigated. We find an anomalous line-width change with temperature. The mode Gruneisen parameter of bulk Ho2O3 was estimated from high pressure Raman investigation up to 29 GPa. Furthermore, the anharmonic components were calculated from the temperature dependent Raman scattering.
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